trans‐Diaquabis(1H‐imidazole‐4,5‐dicarboxylate‐κ2N3,O4)manganese(II) |
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Authors: | Chengbing Ma Feng Chen Changneng Chen Qiutian Liu |
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Abstract: | In the title compound, Mn(C5H3N2O4)2(H2O)2], the MnII atom lies on an inversion centre, is trans‐coordinated by two N,O‐bidentate 1H‐imidazole‐4,5‐dicarboxylate monoanionic ligands Mn—O = 2.202 (3) Å and Mn—N = 2.201 (4) Å] and two water molecules Mn—O = 2.197 (4) Å], and exhibits a distorted octahedral geometry, with adjacent cis angles of 76.45 (13), 86.09 (13) and 89.20 (13)°. The complete solid‐state structure can be described as a three‐dimensional supramolecular framework, stabilized by extensive hydrogen‐bonding interactions involving the coordinated water molecules, the carboxy O atoms and the protonated imidazole N atoms of the imidazole‐4,5‐dicarboxylate ligands. |
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