meso‐5,5,7,12,12,14‐Hexamethyl‐4,11‐diaza‐1,8‐diazoniacyclotetradecane (S)‐malate(2–) methanol disolvate: a chain of rings generated by two pairs of N—H⃛O hydrogen bonds |
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Authors: | Katharine F Bowes George Ferguson Alan J Lough Christopher Glidewell |
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Abstract: | The title compound is a methanol‐solvated salt, C16H38N42+·C4H4O52−·2CH3OH, in which the ionic components are linked into chains by two pairs of N—H⃛O hydrogen bonds H⃛O = 1.78–2.21 Å, N⃛O = 2.702 (14)–3.094 (8) Å and N—H⃛O = 160–179°]. The methanol molecules are pendent from the chain and are linked to it by O—H⃛O hydrogen bonds H⃛O = 1.86 and 1.89 Å, O⃛O = 2.691 (9) and 2.708 (16) Å, and O—H⃛O = 168 and 165°]. |
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