Abstract: | Molecules of the title compound, C14H17N5O4, exhibit a highly polarized molecular–electronic structure. The molecules are linked into sheets by two N—H⋯O hydrogen bonds H⋯O = 2.03 and 2.02 Å, N⋯O = 2.836 (2) and 2.887 (2) Å, and N—H⋯O = 153 and 168°], augmented by a single C—H⋯O hydrogen bond H⋯O = 2.47 Å, C⋯O = 3.403 (2) Å and C—H⋯O = 166°]. Pairs of sheets, related by inversion, form bilayers with interdigitated dimethoxybenzyl substituents, weakly linked by a further C—H⋯O interaction H⋯O = 2.50 Å, C⋯O = 3.350 (2) Å and C—H⋯O = 146°]. |