A new metal-organic open framework consisting of threefold parallel interwoven (6,3) nets |
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Authors: | Suh Myunghyun Paik Choi Hye Jin So Soon Mog Kim B Moon |
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Affiliation: | School of Chemistry and Molecular Engineering, Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Republic of Korea. mpsuh@plaza.snu.ac.kr |
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Abstract: | Threefold parallel interwoven (6,3) nets were assembled from Ni(II) cyclam complex and 1,3,5-tris[2-(4-carboxyphenyl)-1-ethynyl]benzene. The network generates triangular voids of effective size ca. 18.4 x 14.7 x 9.5 A. It contains 35% free volume of the crystal volume and is stable up to 300 degrees C. |
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