Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2)Ru(H)(2)] (dppm = Ph(2)PCH(2)PPh(2)): synthesis and crystal structure of a methanedithiolate complex |
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| Authors: | Gandhi Thirumanavelan Nethaji Munirathinam Jagirdar Balaji R |
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| Institution: | Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India. |
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| Abstract: | Addition of excess carbon disulfide to cis/trans-(dppm)(2)Ru(H)(2)] results in the methanedithiolate complex (dppm)(2)Ru(eta(2)-S(2)CH(2))] 4 via the intermediacy of cis-(dppm)(2)Ru(H)(SC(S)H)] 2. The X-ray crystal structure of this species has been determined. |
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