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Semiconducting behavior of type-I Si clathrate K8Ga8Si38
Authors:Imai Motoharu  Sato Akira  Udono Haruhiko  Imai Yoji  Tajima Hiroyuki
Institution:National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan. IMAI.Motoharu@nims.go.jp
Abstract:A ternary type-I Si clathrate K(8)Ga(8)Si(38) has been revealed to be an indirect band gap semiconducting material with an energy gap (E(g)) of approximately 0.10 eV, which is much smaller than the calculated E(g) value that is 0.15 eV wider than E(g) of elemental Si with the diamond-type structure.
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