Kinetics of the gas‐phase reaction of Cl atoms with CF2ClCFClH at 263–313 K

Relative rate techniques were used to measure k(Cl + CF₂ClCFClH) = (1.4) × 10⁻¹¹ exp[−(2360 ± 400)/T] cm³ molecule⁻¹ s⁻¹; k(Cl + CF₂ClCFClH) = 5.1 × 10⁻¹⁵ cm³ molecule⁻¹ s⁻¹ at 298 K. This result is discussed with respect to the available data. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 785–788, 1999