|
|||||
|
|
Unexpected structural analogy between early and late 3d transition metal alkoxide carboxylates: Synthesis and single crystal X-ray study of Ni6(OH)2(OR)6(OCOR)2, R = C2H4NMe2, R = H, CH3 |
|
| Authors: | Elena Ilina Vadim G Kessler |
| Institution: | aDepartment of Chemistry, Altay State University, Barnaul, Russia bDepartment of Chemistry, SLU, Box 7015, 75007 Uppsala, Sweden |
| Abstract: | Modification of the liquid Ni(ORN)2, RN = C2H4NMe2, with stoichiometric or sub-stoichiometric amounts of carboxylic acids, HCOOH or CH3COOH, results in formation of crystalline heteroleptic complexes Ni6(OH)2(ORN)6(OCOR)2, R = H (1), CH3 (3) with the core structure closely analogous to that observed earlier for hexanuclear titanium (IV) alkoxide carboxylates and derived from hexagonal packing of the donor atoms. |
| Keywords: | Nickel alkoxides Molecular precursors Chemical modification Acidic reagents Hybrid magnetic materials |
| 本文献已被 ScienceDirect 等数据库收录！ | |