Nonameric porphyrin assemblies--formation and intra-assembly energy transfer reactions |
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Authors: | Sasaki Ken Sugou Kenji Miyamoto Koji Hirai Jyun-Ichi Tsubouchi Shigetaka Miyasaka Hiroshi Itaya Akira Kuroda Yasuhisa |
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Institution: | Department of Polymer Science, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan. |
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Abstract: | The nonameric porphyrin assemblies constructed with the series of free base tetraphenylporphyrins Pn having four pyrazine moieties linked with alkyl chains of different lengths, (CH2)n (n = 1, 5, 9, 17, 30), and dimeric meso-tetrakis(2-carboxy-4-nonylphenyl)porphyrinato]zinc(II), ZnP2, show the effective light-collection effect and the typical Forster-type energy transfer from ZnP2 to Pn. |
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