| 椭圆法用于阳极溶出伏安法测定微量银 |
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| 引用本文： | 冉迎春,谢上芬.椭圆法用于阳极溶出伏安法测定微量银[J].分析化学,1997,25(7):807-810. |
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| 作者姓名： | 冉迎春 谢上芬 |
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| 作者单位： | 国家标准物质研究中心(冉迎春)，重庆大学应用化学系!重庆630044(谢上芬，杨雨如，黄宗卿) |
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| 基金项目： | 国家自然科学基金资助课题 |
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| 摘 要： | 用新物理量Ｖｏｐ的椭圆法对阳极溶出伏安法分析的含银离子浓度为１０＾５－１０＾－９ｍｏｌ／Ｌ的一系列溶液进行了研究。结果表明：光学方法与电化学方法所得分析结果相同；椭圆法可检测的浓度下限比电化学方法低一个数量级以上。而且测量的相对平均偏差也小于电化学方法。
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| 关 键 词： | 椭圆法 阳极溶出伏安法 银 |
Investigation on the Ellipsometry for Determination of Silver in Comparison With Anodic Stripping Voltammetry |
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| Ran Yingchun,Xie Shangfen,Yang Yuru,Huang Zongqing.Investigation on the Ellipsometry for Determination of Silver in Comparison With Anodic Stripping Voltammetry[J].Chinese Journal of Analytical Chemistry,1997,25(7):807-810. |
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| Authors: | Ran Yingchun Xie Shangfen Yang Yuru Huang Zongqing |
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| Abstract: | The determination of silver by anodic stripping voltammetry and ellipsometry is compared. It is shown that the analytical results given by both methods are identical and the ellipsometry with a new parameter Vop has a sensitivity higher than that of electrochemical method. |
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| Keywords: | Ellipsomctry optical tracking rate spectroellipsometry |
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