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A model for the thermorheological behavior of viscoelastic fluids
Authors:Dr H Braun
Institution:(1) Freiburger Materialforschungszentrum, Universität Freiburg, Stefan-Meier-Straße 31a, 7800 Freiburg, Germany
Abstract:Using a power-law ansatz for the temperature dependence of the shear modulus on the level of internal variables, the thermorheological behavior is modeled for viscoelastic fluids of a special group of rheological constitutive equations (rate-type models). The model parameter introduced characterizes thermoelastic contributions. The relation between the model parameter and the physical quantities appearing in deformation processes is discussed. Based on the chosen temperature dependence of the shear modulus, thermodynamically consistent equations like the nonlinear rheological constitutive equation and the temperature equation are derived. The special cases of entirely entropy and energy elastic fluids are also considered. The thermorheological behavior (exo-, agr- or endothermal processes) of a viscoelastic fluid in a stress-growth experiment followed by relaxation is analyzed with respect to the model parameter.
Keywords:Viscoelasticity  dissipation in transient flows  nonisothermal rheological constitutive equations  dissipation in transient flows
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