Preparation and upconversion luminescence characterization of 12CaO·7Al2O3:Ho3+/Yb3+ polycrystals

The effect of Yb³⁺ concentration on the fluorescence of 12CaO·7 Al₂O₃:Ho³⁺/Yb³⁺ polycrystals is investigated. The Raman spectra of pure C12A7 under 633‐nm excitation show that the highest photon energy is 787.267 cm^?1, which is not much bigger than general fluorides, so it can realize high efficiency upconversion. The upconversion emission spectra suggest that the green upconversion emission centered at 548 nm and the red upconversion emission at 662 nm correspond to the ⁵F₄/⁵S₂→⁵I₈ and ⁵F₅→⁵I₈ transition of Ho³⁺ ions, respectively. The intensity of the upconversion luminescence and the ratio of red to green are changed with Yb³⁺ ion concentration. The pump dependence and luminescence decay dynamics spectra show the green and red upconversion emissions are populated by a two‐photon process, and the upconversion mechanisms are analyzed. The relative luminous efficiencies of green and red emissions are 2.035% and 0.7%, respectively. The normalized efficiency obtained for green emission of Ho³⁺ at RT when the sample is excited by 980‐nm light with an absorbed intensity of 7.5 W/cm² is 0.27 cm²/W. This result is comparable to the values obtained in YF₃ for the Yb³⁺, Er³⁺ green emission. The C12A7 with upconversion red and green light will be a promising luminous material.