Azines possessing strong push-pull donors/acceptors |
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| Authors: | Choytun Dharinee D Langlois Lisa D Johansson Thomas P Macdonald Charles L B Leach Gary W Weinberg Noham Clyburne Jason A C |
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| Institution: | Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Ave, Windsor ON N9B 3P4, Canada. |
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| Abstract: | Azines (R(2)Cdouble bond, length as m-dash]N-Ndouble bond, length as m-dash]CR(2)) are 2,3-diaza analogues of 1,3-butadiene. In this report we show that strong polarisation of the azine imparts structural features consistent with delocalization within the azine fragment; NLO properties for the azines are also reported. |
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