| 烯基叠氮与二异丙基黄原酸酯的自由基串联反应:合成6-巯甲基菲啶（英文） |
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| 引用本文： | 陆露露,周丙伟,金红卫,刘运奎.烯基叠氮与二异丙基黄原酸酯的自由基串联反应:合成6-巯甲基菲啶（英文）[J].有机化学,2019(2):515-520. |
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| 作者姓名： | 陆露露 周丙伟 金红卫 刘运奎 |
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| 作者单位： | 浙江工业大学化学工程学院绿色化学与技术国家重点实验室培育基地 |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(Nos.21772176,21372201);the Opening Foundation of Zhejiang Key Course of Chemical Engineering and Technology,Zhejiang University of Technology~~ |
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| 摘 要： | 发展了偶氮二异丁腈诱发的烯基叠氮类化合物与二异丙基黄原酸酯的自由基串联反应,一步构建了碳-硫和碳-氮键.以50%至80%的收率方便和高区域选择性地合成了一系列官能化的6-巯甲基菲啶类化合物.机理研究表明该反应通过自由基路径进行.
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| 关 键 词： | 烯基叠氮 二硫化二异丙基黄原酸酯 菲啶 自由基反应 |
Radical-Triggered Tandem Reaction of Vinyl Azides with Isopropylxanthic Disulfide for the Synthesis of 6-Sulfanylmethyl Phenanthridines |
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| Lu Lulu,Zhou Bingwei,Jin Hongwei,Liu Yunkui.Radical-Triggered Tandem Reaction of Vinyl Azides with Isopropylxanthic Disulfide for the Synthesis of 6-Sulfanylmethyl Phenanthridines[J].Chinese Journal of Organic Chemistry,2019(2):515-520. |
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| Authors: | Lu Lulu Zhou Bingwei Jin Hongwei Liu Yunkui |
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| Institution: | (State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014) |
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| Abstract: | Lu Lulu;Zhou Bingwei;Jin Hongwei;Liu Yunkui(State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014) |
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| Keywords: | vinyl azides isopropylxanthic disulfide phenanthridine radical reaction |
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