| 镍催化的偕二氟芳基乙烯与有机锌交叉偶联反应立体选择性合成(Z)-单氟烯烃 |
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| 引用本文： | 张娟,王碧云,刘熠森,曹松.镍催化的偕二氟芳基乙烯与有机锌交叉偶联反应立体选择性合成(Z)-单氟烯烃[J].有机化学,2019(1):249-256. |
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| 作者姓名： | 张娟 王碧云 刘熠森 曹松 |
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| 作者单位： | 上海市化学生物学(芳香杂环)重点实验室华东理工大学药学院 |
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| 基金项目： | 国家自然科学基金(Nos.21472043,21272070)资助项目~~ |
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| 摘 要： | 报道了在Ni Cl2(dppp)催化和氯化锂促进下,室温下将偕二氟芳基乙烯与有机锌试剂进行交叉偶联反应,合成一系列(Z)-单氟烯烃的方法.该方法具有反应条件温和、操作简单、官能团兼容性较好、立体选择性出色等优点.
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| 关 键 词： | 偕二氟芳基乙烯 镍催化 有机锌 单氟烯烃 |
Stereoselective Synthesis of Z-Fluorostyrene Derivatives via Nickel-Catalyzed Cross-Coupling of gem-Difluorostyrenes with Organozinc Reagents |
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| Zhang Juan,Wang Biyun,Liu Yisen,Cao Song.Stereoselective Synthesis of Z-Fluorostyrene Derivatives via Nickel-Catalyzed Cross-Coupling of gem-Difluorostyrenes with Organozinc Reagents[J].Chinese Journal of Organic Chemistry,2019(1):249-256. |
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| Authors: | Zhang Juan Wang Biyun Liu Yisen Cao Song |
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| Institution: | (Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology(ECUST), Shanghai 200237) |
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| Abstract: | Zhang Juan;Wang Biyun;Liu Yisen;Cao Song(Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology(ECUST), Shanghai 200237) |
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| Keywords: | gem-difluorostyrenes nickel-catalyzed organozinc reagents monofluoroalkenes |
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