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Highly stereo- and regioselective synthesis of a phenylene–silylene–vinylene polymer via ruthenium-catalyzed polycondensation |
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| Authors: | Mariusz Majchrzak Yujiro Itami Bogdan Marciniec Piotr Pawluc |
| Affiliation: | Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland |
| Abstract: | [RuCl2(CO)3]2 catalyzed cross-coupling polycondensation of 1,4-bis(vinyldimethylsilyl)benzene (A) appears to be a new, very efficient, method for highly stereo- and regioselective synthesis of phenylene–silylene–vinylene polymers (B). |
| Keywords: | cross-coupling polycondensation phenylene–silylene–vinylene polymers ruthenium(II) complex |
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