Crystal structure of 1,3-di-2-[(4-methoxyphenyl)-1-diazenyl]imidazolidine |
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Authors: | Kumar Biradha Hilary Jenkins M Brad Peori Keith Vaughan Michael J Zaworotko |
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Institution: | (1) Department of Chemistry, Saint Mary's University, Halifax, Nova Scotia, Canada, B3H 2J5;(2) Present address: University of S. Florida, Tampa, FL |
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Abstract: | The crystal and molecular structure of 1,3-di-2-(4-methoxyphenyl)-1-diazenyl]imidazolidine (1) has been determined by single crystal X-ray diffraction analysis. This novel bis-triazene assumes a close-to planar structure with the aryltriazene moieties aligned in diametrically opposed directions, unlike many other previously reported bis-triazenes, which assume a folded structure. The structure of 1 is compared with the closely related, non-cyclic bis-triazene analogue (2), and also compared with the structure of the simple mono-triazene (3). Crystal data: 1 C17H20N6O2, monoclinic, space group C2/c, a = 34.948(3), b = 5.925(5), c = 8.1225(6) Å, = 100.8420(10)°, and V = 1652.0(2) Å3, for Z = 4. |
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Keywords: | crystal structure imidazolidine triazene bis-triazene methoxy substituent -gif" alt="pgr" align="BASELINE" BORDER="0">- stacking" target="_blank">gif" alt="pgr" align="BASELINE" BORDER="0"> stacking |
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