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Effect of Metal Inclusions on the Porous Structure and Photocatalytic Activity of Titanium Dioxide
Authors:Kovalenko  A. S.  Kuchmii  S. Ya.  Makovskaya  T. F.  Korzhak  A. V.  Tsyrina  V. V.  Yats'kiv  V. I.  Il'in  V. G.
Affiliation:(1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03028 Kyiv, Ukraine
Abstract:
A study was carried out on the effect of the inclusion of a series of transition metals (V, Cr, Mn, Fe, Ni, Cu, Zr, Mo) and also Al, Si, Zn, and Sn into titanium dioxide on its porous structure, anatase formation, and photocatalytic activity in the generation of molecular hydrogen from aqueous ethanol. An increase in the content of these metals leads to a decrease in photocatalytic activity, while an increase in the anatase content in titanium dioxide leads to an increase in such activity.
Keywords:titanium dioxide  porous structure  photocatalytic activity
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