Stereochemical study of phosphonothioate cleavage by a metallomicelle |
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Authors: | Moss Robert A Gong Paul K Morales-Rojas Hugo |
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Affiliation: | Department of Chemistry, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. moss@rutchem.rutgers.edu |
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Abstract: | [reaction: see text] The copper metallomicellar hydrolysis of O-methyl O-4-nitrophenyl phenylphosphonothioate to O-methyl phenylphosphonothioic acid takes place with effectively complete inversion at phosphorus. |
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