Polymerization of 1,2,4,5-tetramethylbenzene (durene) in direct-current discharge |
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Authors: | M. Yu. Yablokov A. B. Gil’man N. M. Surin I. V. Semenov A. A. Kuznetsov I. A. Chmutin |
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Affiliation: | 1.Enikolopov Institute of Synthetic Polymer Materials,Russian Academy of Sciences,Moscow,Russia;2.Institute of Nanotechnologies,International Conversion Foundation,Moscow,Russia |
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Abstract: | Polymer films possessing dielectric properties were prepared from 1,2,4,5-tetramethylbenzene (durene) at the cathode in a dc discharge. The chemical structure of the films was studied by IR and UV spectroscopy. It was shown that the polymer synthesized from durene in a dc discharge contains basically polyene structures produced via the opening of aromatic rings. |
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