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A Cationic Water‐Soluble Poly(p‐phenylenevinylene) Derivative: Highly Sensitive Biosensor for Iron‐Sulfur Protein Detection
Authors:Fan Cheng  Guang‐Wei Zhang  Xiao‐Mei Lu  Yan‐Qin Huang  Yi Chen  Ying Zhou  Qu‐Li Fan  Wei Huang
Abstract:Summary: A new water‐soluble cationic ammonium‐functionalized poly(p‐phenylenevinylene) (PPV‐NEtMeurn:x-wiley:10221336:media:MARC200500867:tex2gif-stack-1) was successfully synthesized and exhibited high sensitivity (Ksv = 6.9 × 107 M −1) on rubredoxin, a type of anionic iron‐sulfur (Fe‐S) proteins. Further investigation showed that the biosensitivity of the cationic conjugated polymer is strongly dependent on the nature of the buffer solution and the concentration of the conjugated polymer used in the analyses.
image

The schematic diagram of anionic rubredoxin detected by PPV‐NEtMeurn:x-wiley:10221336:media:MARC200500867:tex2gif-stack-2.

Keywords:morphology  nanocolloid  polyaniline  poly(N‐vinylpyrrolidone)  self‐assembly
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