首页 | 本学科首页   官方微博 | 高级检索  
     


En route to coordination chemistry under confined conditions in a porous capsule: Pr3+ with different coordination shells
Authors:Muller Achim  Zhou Yunshan  Zhang Lijuan  Bogge Hartmut  Schmidtmann Marc  Dressel Martin  Slageren Joris
Affiliation:Fakultat fur Chemie der Universitat, Lehrstuhl fur Anorganische Chemie I, Postfach 100131, D-33501 Bielefeld, Germany. a.mueller@uni-bielefeld.de
Abstract:
The highly charged nanocontainer capsule of the type [pentagon]12[linker]30 identical with [(Mo)Mo5O21(H2O)6]12[Mo2O4(SO4)]30 with 20 nanosized pores and channels allows the entrance of cations like Pr3+: the latter are positioned at two different sites and have two different coordination shells, corresponding to a coordination chemistry under confined conditions; a fascinating aspect is that capsule encapsulated water shells fixed by hydrogen bonds act formally as polydentate ligands.
Keywords:
本文献已被 PubMed 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号