Kinetics and mecahnism of oxidation of benzoins by peroxydisulfate catalyzed by Ag(I) |
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| Authors: | N. C. Khandual |
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| Affiliation: | (1) Department of Chemistry, Ravenshaw College, 753 003 Cuttack, India |
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| Abstract: | The kinetics of Ag(I) catalyzed oxidation of benzoin and four substituted benzoins by peroxydisulfate have been investigated in 30 vol. % acetic acid-water mixture at constant ionic strength. The parameters of Arrhenius and transition state theories have been computed. The rate laws are explained on the basis of a free radical mechanism.
                          ,  Ag(I), (30 .%)  .     .    - .
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