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Oxidation of secondary terpene alcohols by chlorine dioxide
Authors:L L Frolova  A V Popov  S A Rubtsova  A V Kuchin
Institution:(1) Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Russian Federation, 167982, Syktyvkar, ul. Pervomaiskaya, 48, Russia
Abstract:Secondary terpene alcohols cis- and trans-verbenol, neo-iso-verbanol, borneol, iso-borneol, and menthol were oxidized by chlorine dioxide into the corresponding ketones. It was shown that the nature of the solvent and catalyst and the structure of the starting compound, including the stereochemistry of the hydroxyl, influenced the oxidation process. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 585–587, November–December, 2008.
Keywords:cis- and trans-verbenol            neo-iso-verbanol  borneol            iso-borneol  menthol  chlorine dioxide  oxidation  catalysts
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