Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride |
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| Authors: | Rajendran Kamalraj V Gilheany Declan G |
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| Affiliation: | Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland. |
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| Abstract: | ![]()
A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride. |
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