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TiO2-石墨烯光催化剂:制备及引入石墨烯的方法对光催化性能的影响
引用本文:耿静漪,朱新生,杜玉扣.TiO2-石墨烯光催化剂:制备及引入石墨烯的方法对光催化性能的影响[J].无机化学学报,2012,28(2):357-361.
作者姓名:耿静漪  朱新生  杜玉扣
作者单位:1. 苏州大学纺织与服装工程学院,苏州 215123;苏州大学化学化工学院,苏州 215123
2. 苏州大学纺织与服装工程学院,苏州,215123
3. 苏州大学化学化工学院,苏州,215123
摘    要:利用溶胶-凝胶法原位制备了二氧化钛/石墨烯(TiO2-GE)复合光催化剂,研究了纯TiO2以及不同方法制备的TiO2-GE复合光催化剂对亚甲基蓝及罗丹明B光催化降解性能。结果表明:石墨烯的引入提高了TiO2的光催活性,这主要是得益于石墨烯优异的电子传输性能及较好吸附特性。不同方法制备TiO2-GE复合催化剂的光催化活性也存在较大差别。原位制备的TiO2-GE复合光催化剂表现出最佳的光催化活性。

关 键 词:溶胶-凝胶法  TiO2-GE  光催化活性

TiO2-Graphene Photocatalyst: Preparation and Effect of the Introducation of Graphene on Photocatalytic Performance
GENG Jing-Yi,ZHU Xin-Sheng and DU Yu-Kou.TiO2-Graphene Photocatalyst: Preparation and Effect of the Introducation of Graphene on Photocatalytic Performance[J].Chinese Journal of Inorganic Chemistry,2012,28(2):357-361.
Authors:GENG Jing-Yi  ZHU Xin-Sheng and DU Yu-Kou
Institution:College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China,College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China and College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
Abstract:Titania/graphene (TiO2-GE) composite photocatalyst has been in-situ synthesized by sol-gel method. The photocatalytic performance of pure TiO2 and TiO2-GE composite obtained by different methods has been investigated using the photodegradation of methylthionine chloride and rhodamine B as model reactions. The results show that the photocatalytic activity of TiO2-GE composite is much higher than that of pure TiO2 due to rapid electronic transmission and the good adsorption of GE. Additionally, the as-prepared TiO2-GE composites obtained with different preparation methods have different activities in the photodegradation of methylthionine chloride and rhodamine B. The TiO2-GE composite synthesized by in-situ sol-gel method shows the highest photocatalytic activity.
Keywords:sol-gel  TiO2-GE  photocatalytic activity
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