Vibrational Spectroscopic Studies on the tn-Td-Type Mn(tn)Zn(CN)4_2C6H6 and the Chelated tn-Td-Type Zn(tn)Zn(CN)4_2C6H6 Clathrates |
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| Authors: | Ziya Kantarci Celal Bayrak |
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| Institution: | (1) Fen Edebiyat Fakültesi, Fizik A.B.D., Teknikokullar, Gazi Üniversitesi, 06500 Ankara, Turkey |
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| Abstract: | IR spectra of Mn(trimethylenediamine)Zn(CN)42C6H6 and IR and Raman spectra of Zn(trimethylenediamine)Zn(CN)4_2C6H6 are reported. The spectral data suggest that the host frameworks of these compounds are similar to those of the tn-Td-type Cd(trimethylenediamine)M(CN)4_2benzene (M = Cd or Hg) and the chelated pn-Td-type Cd(propylenediamine)Cd(CN)4_1,2-dichloro-ethane clathrates, respectively. |
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| Keywords: | Clathrates inclusion compounds trimethylenediamine tetracyanozincate benzene IR spectra Raman spectra |
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