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| STUDY ON THE SYNTHESIS OF BRASSINOLIDE AND RELATED COMPOUNDS 15.FORMAL SYNTHESIS OF BRASSINOLIDE VIA STEREOSELECTIVE SULFENATE-SULFOXIDE TRANSFORMATION | |
| 引用本文： | Wei Shan ZHOU,Zheng Wu SHEN. STUDY ON THE SYNTHESIS OF BRASSINOLIDE AND RELATED COMPOUNDS 15.FORMAL SYNTHESIS OF BRASSINOLIDE VIA STEREOSELECTIVE SULFENATE-SULFOXIDE TRANSFORMATION[J]. 中国化学快报, 1991, 2(2): 111-114 |
| 作者姓名： | Wei Shan ZHOU Zheng Wu SHEN |
| 作者单位： | Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032 |
| 基金项目： | This investigation was supported by the National Natural Science Fundation of China. |
| 摘 要： | A formal synthesis of the natural growth promoting steroidbrassinolide is described,which involves construction of side chainby 1,3-sulfoxide-hydroxyl transposition with methylation from(24S)-22-E-24-sulfoxide 6 and(24R)-22-E-24-sulfoxide 9,respectively to(22S)-23-E-24-methyl compound 4. |
STUDY ON THE SYNTHESIS OF BRASSINOLIDE AND RELATED COMPOUNDS 15. FORMAL SYNTHESIS OF BRASSINOLIDE VIA STEREOSELECTIVE SULFENATE-SULFOXIDE TRANSFORMATION |
|
| Wei Shan ZHOU,Zheng Wu SHEN. STUDY ON THE SYNTHESIS OF BRASSINOLIDE AND RELATED COMPOUNDS 15. FORMAL SYNTHESIS OF BRASSINOLIDE VIA STEREOSELECTIVE SULFENATE-SULFOXIDE TRANSFORMATION[J]. Chinese Chemical Letters, 1991, 2(2): 111-114 | |
| Authors: | Wei Shan ZHOU Zheng Wu SHEN |
| Affiliation: | Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032 |
| Abstract: | A formal synthesis of the natural growth promoting steroid brassinolide is described, which involves construction of side chain by 1, 3-sulfoxide-hydroxyl transposition with methylation from (24S)-22-E-24-sulfoxide 6 and (24R)-22-E-24-sulfoxide 9, respectively to (22S)-23-E-24-methyl compound 4. |
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