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超高分子量聚乙烯纤维表面改性的研究进展
引用本文:尚晴,赵晗,赵宁,赵义平,尹晓品,丁彩玲,徐坚.超高分子量聚乙烯纤维表面改性的研究进展[J].高分子通报,2020(4):22-29.
作者姓名:尚晴  赵晗  赵宁  赵义平  尹晓品  丁彩玲  徐坚
作者单位:天津工业大学材料科学与工程学院;中国科学院化学研究所高分子化学与物理实验室;山东如意科技集团有限公司
基金项目:山东省重大科技创新工程项目(2018YFJH0103);泰山产业领军人才工程专项经费资助;中国科学院前沿科学重点研究计划项目(QYZDJ-SSW-SLH03)。
摘    要:超高分子量聚乙烯(UHMWPE)纤维具有诸多优异性能,因此被广泛应用于纤维增强复合材料(FRP)。但是由于UHMWPE纤维表面光滑且无极性基团,与树脂基体粘接性差,可通过纤维表面改性有效提高FRP的界面强度,进而提升材料性能。本文总结了近几年基于化学处理、等离子体处理、电晕放电和辐射引发表面接枝等方法对UHMWPE纤维表面改性的研究进展,并对改性方法的发展进行了展望。

关 键 词:纤维增强复合材料  超高分子量聚乙烯  树脂基体  复合界面粘附理论  界面强度

Research Progress on Surface Modification of Ultra-high Molecular Weight Polyethylene Fiber
SHANG Qing,ZHAO Han,ZHAO Ning,ZHAO Yi-ping,YIN Xiao-pin,DING Cai-ling,XU Jian.Research Progress on Surface Modification of Ultra-high Molecular Weight Polyethylene Fiber[J].Polymer Bulletin,2020(4):22-29.
Authors:SHANG Qing  ZHAO Han  ZHAO Ning  ZHAO Yi-ping  YIN Xiao-pin  DING Cai-ling  XU Jian
Institution:(State Key Laboratory of Separation Membranes and Membrane Processes,School of Material Science and Engineering,Tiangong University,Tianjin 300387,China;Laboratory of Polymer Chemistry and Physics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China;Shandong Ruyi Technology Group Co.,Ltd.,Jining 272073,China)
Abstract:Ultra-high molecular weight polyethylene(UHMWPE)fibers are widely used in fiber reinforced polymers(FRP)because of their excellent properties.However,UHMWPE fibers inherently exhibit poor adhesion owing to the low surface free energy and the lack of polar functional groups,which affect the performance of the composites and limit their application.Surface modification can effectively increase the interface strength of FRP and thus improve the properties of the materials.In this review,the recent research progress on the surface modification of UHMWPE fibers,with the emphasis on chemical treatment,plasma treatment,corona discharge and radiation-induced surface grafting method,has been summarized,and the development of modification method is prospected.
Keywords:FRP  UHMWPE  Surface modification  Interface
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