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In situ controlled promotion of catalyst surfaces via solid electrolytes: Ethylene oxidation on Rh and propylene oxidation on Pt
Authors:A. C. Kaloyannis  C. A. Pliangos  I. V. Yentekakis  C. G. Vayenas
Affiliation:1. Department of Chemical Engineering and ICE/HT, University of Patras, GR-26500, Patras, Greece
Abstract:
The kinetics of C2H4 oxidation on Rh and C3H6 oxidation on Pt were investigated on polycrystalline metal films interfaced with ZrO2(8mol%Y2O3) solid electrolyte in galvanic cells of the type:

$$begin{gathered}  C_2 H_4 ,O_2 ,Rh/YSZ/Pt,O_2  and hfill   C_3 H_6 ,O_2 ,CO_2 ,Pt/YSZ/Au,C_3 H_6 ,O_2 ,CO_2  hfill  end{gathered} $$
Keywords:
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