Enantioselective synthesis utilizing enantiomorphous organic crystal of achiral benzils as a source of chirality in asymmetric autocatalysis |
| |
| Authors: | Kawasaki Tsuneomi Harada Yuuki Suzuki Kenta Tobita Takayuki Florini Nicola Pályi Gyula Soai Kenso |
| |
| Institution: | Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan. |
| |
| Abstract: | Chiral crystals of achiral benzils act as efficient chiral initiators of asymmetric autocatalysis to afford highly enantioenriched pyrimidyl alkanols whose absolute configurations depend upon the enantiomorph of the crystal used in conjunction with asymmetric autocatalysis with amplification of enantiomeric excess. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
