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Photoluminescence in Gd2O3: Er3+, Yb3+ upconversion inverse opal
Authors:Zhengwen Yang  Dong Yan  Hangjun Wu  Rongfei Wang  Zhiguo Song  Dacheng Zhou  Xue Yu  Yong Yang  Zhaoyi Yin  Lei Yan  Jianbei Qiu
Affiliation:Key Lab of Advanced Materials in Rare & Precious and Non-ferrous Metals, Ministry of Education, Key Laboratory of Advanced Materials of Yunnan Province, College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
Abstract:Photoluminescence properties of Gd2O3: Er3+, Yb3+ upconversion inverse opal photonic crystals were investigated. The photoluminescence spectra of the inverse opal show strong dependence on upconversion emission intensity and the corresponding photonic band-gaps of the inverse opal. Significant suppression of the green or red upconversion emission was observed if the photonic band-gap overlaps with the Er3+ ions emission band. The color purity of the red or green emission was improved in the inverse opal by the suppression of green or red UC emission. We believe that the present work will be valuable for not only the foundational study of upconversion emission modification but also new optical devices in upconversion lighting and display.
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