{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]36-: a molecular quantum spin icosidodecahedron |
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| Authors: | Botar Bogdan Kögerler Paul Hill Craig L |
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| Institution: | Department of Chemistry, Emory University, Atlanta, GA 30322, USA. bbotar@emory.edu |
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| Abstract: | Self-assembly of aqueous solutions of molybdate and vanadate under reducing, mildly acidic conditions results in a polyoxomolybdate-based {Mo72V30} cluster compound Na8K16(VO)(H2O)5K10 subset{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20].150H2O, 1, a quantum spin-based Keplerate structure. |
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