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Investigation of structural and compositional changes in silver-doped GeO2 thin films
Authors:Svetlana V. Serezhkina  Elena A. Tyavlovskaya  Sergey K. Rakhmanov
Affiliation:a Physico-Chemical Research Institute, Belorussian State University, ul. Leningradskaya 14, Minsk 220080, Belarus
b Institute of Electronics, National Academy of Sciences of Belarus, Logoisky trakt 22, Minsk 220090, Belarus
c Belorussian State University, prosp. Skoriny 4, Minsk 220050, Belarus
Abstract:
The processes going on in silver-doped GeO2 films during air-heating were investigated by XPS, TEM, IR and UV-visible spectroscopy methods. Silver was shown to interact with the GeO2 matrix at 500-600 °C to give silver germanate which was decomposed on further heating to form GeO2 and silver nanoparticles, 10-35 nm in size, absorbing in the plasmon resonance region (λmax = 415 nm). The silver nanoparticles are located deep in the films and encapsulated by oxide particles.
Keywords:N105   G140
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