The cyclometallation of bis(di-p-methylbenzylphosphino)methane |
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| Authors: | Alberto Ferná ndez |
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| Affiliation: | Departamento de Química Inorgánica, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela, Spain |
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| Abstract: | ![]()
The new diphosphine (4-MeC6H4CH2)2PCH2P(4-MeC6H4CH2)2, L, was reacted with [MnMe(CO)5] to give the novel cyclometallated compound [Mn{(4-MeC6H3CH2)(4-MeC6H4CH2)PCH2P(4-MeC6H4CH2)2}(CO)3], as the mer isomer, and with the ligand in a terdentate [C,P,P] fashion. |
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| Keywords: | Palladium Cyclometallation Phosphines |
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