Mesogens based on palladium orthometallated complexes with carboxylato bridges: tuning and shaping a non-planar molecule |
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Authors: | Laura Díez Jesús A Miguel M Paz Rodríguez-Medina |
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Institution: | Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47005 Valladolid, Spain |
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Abstract: | The binuclear cyclopalladated compounds Pd2(μ-OH)2(Ln)2] (1) derived from imines HLn = p-CnH2n + 1O-C6H4-CHN-C6H4-OCnH2n + 1-p (n = 6,10) react with carboxylic acids to give the derivatives Pd2(μ-ox)2(Ln)2] (2) with a planar core for oxalic acid, and Pd2(μ-OOCR)2(Ln)2] (3-7) compounds with a non-planar ridge tent structure for other RCOOH acids: (3) R = CmH2m + 1 (m = 1, 3, 5, 7, 9, 11, 13, 15, 17); (4) R = CH2(OCH2CH2)pOCH3 (p = 1, 2); (5) R = CH2-C6H4-OCqH2q + 1-p (q = 2, 4, 6, 8, 10, 12); (6) R = C6H4-OCrH2r + 1-p (r = 4, 10); (7) R = C*H(OH)CH3. The acids used were designed to explore the effect on the thermal properties of the compounds prepared of systematic variations in the type of carboxylato ligand, which induce structure, packing, and polarity changes, and in the length of the carboxylato chain. Most of the complexes prepared, even when far from planar, show liquid crystal behavior and display nematic, smectic A and smectic C phases. |
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Keywords: | Metallomesogens Palladium Orthometalated imine Carboxylato Liquid crystals |
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