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Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives |
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| Authors: | Alexander D Dilman Dmitry E Arkhipov Valentine P Ananikov Vladimir A Tartakovsky |
| Institution: | a N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation b Moscow Chemical Lyceum, 109033 Moscow, Tamozhennyi pr. 4, Russian Federation c A. N. Nesmeyanov Institute of Organoelement Compounds, 119991 Moscow, Vavilov str. 28, Russian Federation |
| Abstract: | A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations. |
| Keywords: | Organosilicon chemistry Tris(pentafluorophenyl)silyl derivatives Trichlorosilanes Structural studies |
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