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Organometallic compounds of Group 13 elements containing the ligand C(SiMe3)2(SiMe2C5H4N-2) |
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| Authors: | James Howson Peter B. Hitchcock J. David Smith |
| Affiliation: | a Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK b Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK |
| Abstract: | The lithium derivative  (1) reacted with AlCl3 or Me2AlCl to give, respectively, the monomeric compounds  (2a) and  (2b). The product from reaction with commercially available GaBr3 was the analytically pure monomeric heterocycle  (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl3 gave a homogenous white solid  (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined. |
| Keywords: | Aluminium Gallium Indium Organosilicon Metallacycles |
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