| 流动注射纳米微反应器化学发光法测定盐酸阿米替林 |
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| 引用本文： | 朱乾华.流动注射纳米微反应器化学发光法测定盐酸阿米替林[J].分析试验室,2011,30(6):39-42. |
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| 作者姓名： | 朱乾华 |
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| 作者单位： | 长江师范学院化学化工学院,涪陵,408100 |
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| 基金项目： | 重庆市科委项目，重庆市科涪陵区科委项目 |
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| 摘 要： | 在酸性条件下,盐酸阿米替林分子中氮原子被质子化后与阴离子AuCl4-形成离子缔合物,该缔合物被二氯甲烷带入鲁米诺的氯化十六烷基三甲基铵反胶束纳米微反应器中,离解出来的AuCl4-立即与鲁米诺产生化学发光.在一定浓度范围内,发光强度与盐酸阿米替林的含量成线性关系,从而间接测定盐酸阿米替林的含量.在优化的实验条件下,线性范...
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| 关 键 词： | 纳米微反应器 盐酸阿米替林 化学发光 |
Chemiluminescence analysis of amitriptyline hydrochloride with a nanometer microreactor |
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| ZHU Qian-hua.Chemiluminescence analysis of amitriptyline hydrochloride with a nanometer microreactor[J].Chinese Journal of Analysis Laboratory,2011,30(6):39-42. |
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| Authors: | ZHU Qian-hua |
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| Institution: | ZHU Qian-hua(College of Chemistry and Chemical Engineering,Yangtze Normal University,Fuling 408100) |
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| Abstract: | In acidic condition,the nitrogen in amitriptyline hydrochloride was easily protonated and formed ion associated-complex with negative ion AuCl-4,the ion associated-complex was extracted and carried by dichloromethane,when the ion associated-complex entered a reversed micellar nanometer microreactor of cetyltrimethylammonium chlorine containing luminol,the dissociated AuCl4-reacted with luminol and produced an analytical chemiluminescence signal.Under the optimum conditions,the linear range is from 0.001 to ... |
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| Keywords: | Nanometer microreactor Amitriptyline hydrochloride Chemiluminescence |
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