| 聚合物假冠醚研究 (III)新型聚合物氮杂假冠醚的合成与吸附性能 |
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| 引用本文： | 刘淑芬,郑科,纪春暖,孙言志,曲荣君,宿刚,范美娜. 聚合物假冠醚研究 (III)新型聚合物氮杂假冠醚的合成与吸附性能[J]. 离子交换与吸附, 2003, 0(1) |
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| 作者姓名： | 刘淑芬 郑科 纪春暖 孙言志 曲荣君 宿刚 范美娜 |
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| 作者单位： | 烟台师范学院化学系，烟台燃气研究所，烟台师范学院化学系，烟台师范学院化学系，烟台师范学院化学系 烟台264025，烟台264000，烟台264025，烟台264025，烟台264025，2002年本拉毕业生，2002年本拉毕业生 |
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| 基金项目： | 国家自然科学基金 (29906008)，山东省自然科学基金 (Q99B15)，烟台师范学院科研基金 |
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| 摘 要： | 以苯酚为起始剂,用先聚合后功能基化和Na离子模板的简捷方法合成了一种新型聚合物-氮杂假冠醚。研究了其对金属离子的静态吸附性能,结果表明,聚合物对Na+ 和Ca2+离子具有良好的选择吸附性能,对浓度为0.026mol/L~0.028mol/L的Na+ 和Ca2+的静态吸附容量分别达2.54mmol/g和3.06mmol/g;通过红外光谱研究了聚合物及其与Na+ 和Ca2+的配合物的结构,结果表明,在吸附聚合物中,不仅-CH2OCH2-和-CH2NCH2-参与了配位, -CH2OH和PhOCH2- 亦不同程度地参与了配位。[( )-0.1( )] |
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| 关 键 词： | 聚合物氮杂假冠醚 合成 吸附 金属离子 |
STUDIES ON POLYMER CROWN (I) Synthesis and Adsorption Properties of Novel Polymetic Pseudo Azacrown Ether |
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| LIU Shufen Zheng Ke JI Chunnuan SUN Yanzhi QU Rongjun SU Gang FAN Meina. STUDIES ON POLYMER CROWN (I) Synthesis and Adsorption Properties of Novel Polymetic Pseudo Azacrown Ether[J]. Ion Exchange and Adsorption, 2003, 0(1) |
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| Authors: | LIU Shufen Zheng Ke JI Chunnuan SUN Yanzhi QU Rongjun SU Gang FAN Meina |
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| Affiliation: | LIU Shufen1 Zheng Ke2 JI Chunnuan1 SUN Yanzhi1 QU Rongjun1 SU Gang1 FAN Meina1 1 Department of Chemistry,Yantai Normal College,Yantai 264025 2 Yantai Institute of Goal gas,Yantai 264025 |
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| Abstract: | Phenol as starting material, a novel polymetic pseudo azacrown ether were synthesized by short cut methods of first polymerization, then functionalization and Na+ as template guided, Its static adsorption properties for metal ions were studied. The results showed that the polymer has good selective adsorption properties for Na+ and Ca2+, the capacities of absorption were 2.54mmol/g and 3.06mmol/g respectively at the concentration of 0.026mol/L ~0.027mol/L. The structures of the polymer and complexes with Na+, Ca2+ were studied by FTIR spectroscopy. The results showed that not only could -CH2-O-CH2- and --2|2CHNCH chelate metal ion, but also -CH2OH and PhoCH2- did to a certain extent in the above mentioned complexes in the above mentioned complexes. |
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| Keywords: | Polymetic pseudo azacrown ether Synthesize Adsorption. |
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