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Diastereoselective dearomatization of resorcinols directed by a lactic acid tether: unprecedented enantioselective access to p-quinols
Authors:Mejorado Lupe H  Hoarau Christophe  Pettus Thomas R R
Affiliation:Department of Chemistry and Biochemistry, University of California at Santa Barbara, Santa Barbara, California 93106-9150, USA.
Abstract:
An operationally simple oxidative dearomatization of resorcinol derivatives is reported that employs an inexpensive chiral directing group. The method provides access to a variety of p-quinol derivatives in good yield and diastereoselectivity. A short reductive process affords 4-hydroxy-4-alkylcyclohexenone derivatives in excellent yields and enantiomeric excesses.
Keywords:
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