| Dawson结构钼磷酸的合成与表征 |
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| 引用本文： | 吴通好,李建庆.Dawson结构钼磷酸的合成与表征[J].高等学校化学学报,1991,12(10):1373-1377. |
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| 作者姓名： | 吴通好 李建庆 |
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| 作者单位： | 吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系 长春 130023，长春 130023，长春 130023，长春 130023，长春 130023，长春 130023，长春 130023 |
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| 摘 要： | 合成了H_6P_2Mo_(18)O_(62)杂多酸及其四丁基铵盐和四丁基鏻盐,用IR、~(31)P NMR、GV等手段核查其纯度并研究了热稳定性、酸性和氧化还原性。结果表明,Dawson结构钼磷酸较Keggin结构钼磷酸有更强的氧化性。
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| 关 键 词： | Dawson结构 钼磷酸 合成 表征 |
The Synthesis and Characterization of Molybdophosphoric Acid with Dawson Structure |
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| Wu Tong-hao,Li Jian-qing,Yang Hong-mao,Wang Guo-jia,Zhang Heng-bin,Wei Quan,Jiang Yu-zi.The Synthesis and Characterization of Molybdophosphoric Acid with Dawson Structure[J].Chemical Research In Chinese Universities,1991,12(10):1373-1377. |
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| Authors: | Wu Tong-hao Li Jian-qing Yang Hong-mao Wang Guo-jia Zhang Heng-bin Wei Quan Jiang Yu-zi |
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| Abstract: | The molybdophosphoric acid with Dawson structure and its tetrabutylammonium, tetrabutylphosphorium salts were synthesized. Their purities were checked by IR, 31P NMR and cyclic voltammetry, and their thermal stabilities, acidities and redox properties were also studied. The results ' show that the molybdophosphoric acid with Dawson structure should have stronger oxidizability than that with of the acid Keggin one. |
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| Keywords: | Molybdophosphoric acid with Dawson structure IR spectra Characterization |
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