Synthesis, structure and characterization of binuclear silver(I) complexes |
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| Authors: | Yang Ruina Hou Yimin Xue Baoyu Wang Dongmei Jin Douman |
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| Affiliation: | (1) Henan Institute of Chemistry, 450003 Zhengzhou, P.R. China |
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| Abstract: | ![]()
Summary Two binuclear AgI complexes, [{Ag(dppp)}2](NO3)2 (1) and [{Ag(dppb)}2(NO3)]2 (2) (dppp = Ph2P(CH2)3PPh2, dppb = Ph2P(CH2)4PPh2], were synthesized and characterized by elemental analysis, t.g., i.r. and 31P-n.m.r. spectra. Single crystals of complex (2) were obtained from MeOH-CHCl3. The X-ray crystal structure shows that the dppb ligand is bidentate, with two ligands bridging two metal ions to form a centrosymmetric dimer. |
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