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Decomposition of Methylene Blue in Water by Corona Discharges
Authors:Monica Magureanu  Daniela Piroi  Florin Gherendi  Nicolae Bogdan Mandache  Vasile Parvulescu
Institution:1.Department of Plasma Physics and Nuclear Fusion,National Institute for Lasers, Plasma and Radiation Physics,Bucharest-Magurele,Romania;2.Faculty of Chemistry, Department of Chemical Technology and Catalysis,University of Bucharest,Bucharest,Romania
Abstract:The decomposition of methylene blue (MB) in aqueous solution was investigated using a pulsed corona discharge. The discharge was ignited in the gas bubbled in the solution through several needle electrodes. The influence of treatment time, volume of the treated solution and initial concentration of the dye in solution on MB degradation was studied. The effect of the nature of the gas introduced was also investigated. For the same energy input, MB conversion increased in the order air < argon < oxygen. When using oxygen, the decomposition of MB exceeded 95% after ~20 min plasma treatment. Higher efficiency was obtained for higher treated volume and higher initial concentration. At 90% conversion the yield obtained with oxygen was ~5 g/kWh for an initial concentration of 150 mg/l and a treated volume of solution of 100 ml.
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