Effect of a magnetic field on the kinetics of the annihilation of triplet exciplexes |
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Authors: | P. P. Levin V. A. Kuz'min |
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Affiliation: | (1) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The application of an external magnetic field leads to a lower rate of annihilation of triplet exciplexes in media with sufficiently high dielectric constant, in which the dissociation of the exciplexes to radical-ions is observed. The magnetic effect is explained in the framework of a hyperfine interaction mechanism for singlet-triplet transitions in radical pairs.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2611–2614, November, 1987. |
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