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Novel luminescent hexanuclear platinum(II) alkynyl complex: molecular lego from a face-to-face dinuclear platinum(II) building block
Authors:Hui Chi-Kuen  Chu Ben Wai-Kin  Zhu Nianyong  Yam Vivian Wing-Wah
Affiliation:Center for Carbon-Rich Molecular and Nano-scale Metal-based Materials Research, Department of Chemistry, Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, PR China.
Abstract:
A novel luminescent hexanuclear platinum(II) complex, [Pt(2)(mu-dppm)(2)(C[triple bond]CC(5)H(4)N)(4)[Pt(trpy)](4)](CF(3)SO(3))(8) (trpy = 2,2':6',2'-terpyridine), was successfully synthesized by using the face-to-face dinuclear platinum(II) ethynylpyridine complex [Pt(2)(mu-dppm)(2)(C[triple bond]CC(5)H(4)N)(4)] as the building block.
Keywords:
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