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Carbamic acid 2-trimethylsilylethyl ester as a new ammonia equivalent for palladium-catalyzed amination of aryl halides |
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| Authors: | Dibakar Mullick Prakash Anjanappa Kumaravel Selvakumar Kandasamy Ruckmani Manickam Sivakumar |
| Affiliation: | a Synthetic Chemistry, Syngene International Ltd, Biocon Park, Plot 2 & 3, Jigani Link Road, Bommasandra Industial Area, Bangalore 560 099, India b Bharathidasan Institute of Technology, Bharathidasan University, Tiruchirappalli 620 024, India c Department of Pharmaceutical Technology, Anna University, Tiruchirappalli 620 024, India d Department of Chemical & Environmental Engineering, University of Nottingham (Malaysia campus), Semenyih 43500, Malaysia |
| Abstract: | Carbamic acid 2-trimethylsilylethyl ester (Teoc-NH2) serves as an ammonia equivalent in the palladium-catalyzed amination of aryl bromides and aryl chlorides. Anilines with sensitive functional groups can be readily prepared using these amine derivatives. |
| Keywords: | Palladium catalysis Ammonia surrogates Cross-coupling Carbamic acid 2-trimethylsilylethyl ester |
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