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The Aggregation Kinetics of Colloidal Particles of Basic Yttrium Carbonate
作者姓名:Hui WANG  Zun Sheng CAI  Yin Ming PAN  Xue Zhuang ZHAO
作者单位:Hui WANG; Zun Sheng CAI;Yin Ming PAN; Xue Zhuang ZHAO(Department of Chemistry,)Ying Li AN; (The State Key Laboratory of Functional Polymer Meterials for Absorption and Separation,)Shi Yi GUO; (The Electron Microscope Labrotory of College of Life ScienceNa
摘    要:Studyofthegrowthprocessofcolloidalparticlesofnonequilibriumandirreversibilityisanactiveareaofresearch.Therecognitionofcolloidalaggregatesasfractalobjectshasinspiredalargenumberofexperimentalandtheoreticalstudiesonthestructuralandkineticaspectsofaggregationprocesses"'.Morerecently,kineticsofhematiteaggregationbypolyacrylicacidhavebeenstudiedbyzhangandBume3.Theprimaryhematiteparticleswerequiteuniformandfairlyspherical.Inthispaper,wewillreportthesizeevolutionoffractalaggregatesofinitiallypolydis…


The Aggregation Kinetics of Colloidal Particles of Basic Yttrium Carbonate
Hui WANG, Zun Sheng CAI,Yin Ming PAN, Xue Zhuang ZHAO.The Aggregation Kinetics of Colloidal Particles of Basic Yttrium Carbonate[J].Chinese Chemical Letters,1998(12).
Authors:Hui WANG  Zun Sheng CAI  Yin Ming PAN  Xue Zhuang ZHAO
Abstract:The aggregation kinetics of basic yttrium carbonate pericles in aqueous solution havebeen studied using dynamic light-scattering techniques. In 1.00mol/l NaCl solution fast diffusionlimited aggregation behavior was observed with an increase in aggregate size over time describedby a power law. The aggregates are characterized by a fractal dimension D=1.82. Smoluchowskiand fractal theories were used to characterize the aggregation mechanism and to obtain theaggregation rate constant.
Keywords:Basic yttrium carbonate  fractal aggregate  aggregation kinetics
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