N–N2 state to state vibrational-relaxation and dissociation rates based on quasiclassical calculations |
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| Authors: | F Esposito I Armenise M Capitelli |
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| Institution: | 1. IMIP-CNR (Istituto di Metodologie Inorganiche e dei Plasmi, Consiglio Nazionale delle Ricerche), Via Amendola 122/D, 70126 Bari, Italy;2. Chemistry Department, Bari University, Via Orabona 4, 70126 Bari, Italy |
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| Abstract: | Interpolation formulas are presented to reproduce the rate coefficients for vibrational–translational energy exchange and dissociation for the N + N2 collision process. The original data have been obtained by quasiclassical method in a detailed way, including the effect of molecular rotation. The fitting procedure results are compared with original data and the related error is evaluated. Comparison with global experimental dissociation results is also presented. |
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| Keywords: | Vibrational energy exchange Rate coefficients Dissociation Atom-molecule collisions Nitrogen |
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