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Nuclear magnetic resonance spectral study of 2-acetylpyridine4 N-alkylthiosemicarbazones and their cobalt(III) complexes
Authors:Douglas X West  Brenda L Mokijewski  Haileselassie Gebremedhin  Timothy J Romack
Institution:1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA
Abstract:1H and13C n.m.r. spectra are reported for a series of 2-acetylpyridine4 N-alkylthiosemicarbazones in order to study the effect of increased size of the alkyl function on the ratio of isomers present in solution. Similarly, n.m.r. data for the bis(thiosemicarbazone)cobalt(III) complexes are included, as well as these complexes' ligand field parameters. TMC 2698
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